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Metoprolol succinate (Toprol XL) is a prescription beta-blocker used to treat high blood pressure, chest pain (angina), and heart failure, and to improve survival after a heart attack. It works by slowing the heart rate and relaxing blood vessels, making it easier for the heart to pump blood. Metoprolol succinate is an extended-release form, usually taken once daily. Metoprolol succinate is available only with a prescription and should be taken exactly as directed by a healthcare provider.